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991.
A sensitive spectrophotometric method has been developed for determination of ametryn in agricultural samples. The proposed
method was based on reaction with pyridine and further coupling with sulfanilic acid to form a colored product. The absorbance
was measured at 400 nm with a molar absorptivity of 2.1 × 105 L mol−1 cm−1. The method shows a linear range from 0.2–20 μg mL−1 with limit of detection and limit of quantification 0.16 and 0.54 μg mL−1, respectively. The method has been successfully applied to the determination of ametryn in sugarcane juice and commercial
formulations after separation of ametryn from triazine herbicides based on solvent extraction. Recovery values were found
to be in the range of 96.0 ± 0.2% to 98.4 ± 0.1%. 相似文献
992.
Müller CE Gerecke AC Alder AC Scheringer M Hungerbühler K 《Environmental pollution (Barking, Essex : 1987)》2011,159(5):1419-1426
Anthropogenic perfluorinated compounds (PFCs), especially the perfluoroalkyl acids (PFAAs) are ubiquitously found in surface waters around the globe. Emissions from households, industries and also atmospheric transport/deposition are discussed as the possible sources. In this study, these sources are evaluated using Switzerland as the study area. Forty-four surface water locations in different rivers and an Alpine lake were investigated for 14 PFAAs, four precursors and acesulfame, an artificial sweetener used as a population marker. Concentrations of individual PFAAs were generally low, between 0.02 and 10 ng/L. Correlation analysis showed that some PFAAs concentrations correlated well with population and less with catchment area, indicating that emissions from population, i.e., from consumer products, is the most important source to surface waters in Switzerland. The correlation with the population marker acesulfame confirmed this observation but highlighted also a few elevated PFAA levels, some of which could be attributed to industrial emissions. 相似文献
993.
This article considers a planner’s optimum control exercise with environmental pollution and derives a testable link between
the growth rates of consumption and pollution. The link is then empirically estimated for the case of CO2 emissions for a sample consisting of the union of top 25 countries in terms of CO2 emissions, population and per capita GNP. The analysis suggests that the interrelationship between the growth rates of CO2 emission and economic development is mostly significant for countries that have a high level of CO2 emissions and population. 相似文献
994.
Bai S Srikantaswamy S Krishnanandan V Naik OP 《Environmental monitoring and assessment》2012,184(1):239-249
Urban wastewater treatment leads to the generation of large quantities of biosolids. Accumulation of biosolids is a problem
of environmental relevance due to the existence of heavy metals in the biosolids. Determination of total metal in biosolid
provides information relating pollution levels. Determination of their mobilization capacity and behaviour in the environment
is an important task. An experimental approach commonly used for studying the mobility, transport and bioavailability of metal
in biosolids is the use of selective sequential extraction procedure. In the present study an attempt has been made to study
the heavy metal properties in biosolid samples collected from urban wastewater treatment plants located at Mysore, Karnataka.
Few heavy metals selected for the present study are cadmium, chromium, copper, iron, nickel and zinc. The concentration of
these metals in biosolids and their partition in different fractions are studied. The speciation of metals based on the sequential
extraction scheme was carried out. The concentration of heavy metals is lower than that established by European legislation.
The residual fraction has the maximum percentage of heavy metals whereas, only a small fraction of heavy metals (Fe, Zn and
Cd) are extracted in the most soluble fractions, exchangeable and carbonate fractions. 相似文献
995.
María del Mar Delgado Vincenzo Penteriani Vilis O. Nams Letizia Campioni 《Behavioral ecology and sociobiology》2009,64(1):35-43
Moving and spatial learning are two intertwined processes: (a) changes in movement behavior determine the learning of the
spatial environment, and (b) information plays a crucial role in several animal decision-making processes like movement decisions.
A useful way to explore the interactions between movement decisions and learning of the spatial environment is by comparing
individual behaviors during the different phases of natal dispersal (when individuals move across more or less unknown habitats)
with movements and choices of breeders (who repeatedly move within fixed home ranges), that is, by comparing behaviors between
individuals who are still acquiring information vs. individuals with a more complete knowledge of their surroundings. When
analyzing movement patterns of eagle owls, Bubo bubo, belonging to three status classes (floaters wandering across unknown environments, floaters already settled in temporary
settlement areas, and territory owners with a well-established home range), we found that: (1) wandering individuals move
faster than when established in a more stable or fixed settlement area, traveling larger and straighter paths with longer
move steps; and (2) when floaters settle in a permanent area, then they show movement behavior similar to territory owners.
Thus, movement patterns show a transition from exploratory strategies, when animals have incomplete environmental information,
to a more familiar way to exploit their activity areas as they get to know the environment better. 相似文献
996.
Thomas H. Hutchinson Amanda Beesley Patricia E. Frickers James W. Readman Jenny P. Shaw Jürg Oliver Straub 《Environment international》2009,35(6):931-936
In case of an avian-influenza-derived human flu pandemic, an inordinately high use of medicines over several weeks is predicted, in particular for the recommended influenza antiviral oseltamivir (Tamiflu). While the risk of oseltamivir to sewage works and freshwater bodies has already been assessed, the fact that a large percentage of the human population worldwide lives relatively close to the sea raises concern for its environmental compatibility in coastal marine waters. The potential risk of high oseltamivir use to the marine compartment is assessed in this publication, based on the 2003 European Community Technical Guidance Document (TGD) for risk assessment. Subchronic embryo–larval ecotoxicity tests with three marine invertebrates (Pomatoceros triqueter, Annelida; Mytilus edulis, Mollusca; Paracentrotus lividus, Echinodermata) and chronic growth inhibition tests with two different groups of marine microalgae (Isochrysis galbana, Haptophyta; Skeletonema costatum, Heterokontophyta) were performed with the active substance oseltamivir carboxylic acid to derive a dependable marine predicted no-effect concentration (PNEC). This was compared to a predicted environmental concentration (PEC) for oseltamivir in coastal waters, based on the worst-case freshwater PEC. The PEC/PNEC risk characterisation ratio for the marine compartment is well below 1, which in the terminology of the TGD signifies no immediate concern. Further, while oseltamivir may be persistent (P), it is not bioaccumulative (B) nor highly ecotoxic (T) and therefore not a PBT substance. In conclusion, even a high pandemic use of oseltamivir would not lead to a significant risk for the marine compartment, in confirmation of the risk assessment for sewage works and freshwaters. 相似文献
997.
One of the major consequences of global warming is a rise in sea surface temperature which may affect the survival of marine
organisms including phytoplankton. Here, we provide experimental evidence for heat-induced cell death in a symbiotic microalga.
Shifting Symbiodinium microadriaticum from 27 to 32°C resulted in an increase in mortality, an increase in caspase 3-like activity, and an increase in nitric oxide
(NO) production. The caspase-like activity was strongly correlated with the production of NO in thermally challenged microalgae.
For this experiment, the application of Ac-DEVD-CHO, a mammalian caspase 3-specific inhibitor, partly prevented (by 65%) the
increase in caspase-like activity. To verify the relationship between NO and the caspase-like activity, S. microadriaticum were subsequently incubated with 1.0 mM of the following chemical NO donors: sodium nitroprusside (SNP), S-nitrosoglutathione (GSNO), S-nitroso-N-acetylpenicillamine (SNAP) and 3,3bis(Aminoethyl)-1-hydroxy-2-oxo-1-triazene (NOC-18). The supplementation of both SNP and
NOC-18 caused a significant increase in caspase-like activity compared to the control treatment. Pre-treatment of the microalgae
with the inhibitor Ac-DEVD-CHO before the supplementation of the different NO donors completely prevented the increase in
caspase-like activity. These results suggest that NO could play a role in the induction of cell death in heat-stressed S. microadriaticum by mediating an increase in caspase-like activity. 相似文献
998.
Payments for Environmental Services in Latin America as a Tool for Restoration and Rural Development
Payments for Environmental Services (PES) can encourage projects that enhance restoration, production, and rural development.
When projects promote differentiated systems by paying farmers for the provision of services, the application of PES requires
evaluation of the environmental services provided by each system. We present evaluations of carbon stocks and biodiversity
in pure and mixed native tree plantations in Costa Rica. To illustrate how monetary values can be assigned, we discuss a project
that awarded PES to silvopastoral systems in Costa Rica, Nicaragua, and Colombia based on carbon stocks and biodiversity.
PES can promote positive environmental attitudes in farmers. Currently this project is being scaled up in Colombia based on
their positive experiences with PES as a tool to promote adoption. Compared to PES systems that include only one environmental
service, systems that incorporate bundling or layering of multiple services can make sustainable land uses more attractive
to farmers and reduce perverse incentives. 相似文献
999.
Fukushima fallout in Northwest German environmental media 总被引:1,自引:0,他引:1
Traces of short- and long-lived fallout isotopes (131I, 134Cs and 137Cs) were found in environmental samples collected in Northwest Germany (rain water, river sediment, soil, grass and cow milk) from March to May 2011, following the radioactivity releases after the nuclear accident in Fukushima, Japan. The measured concentrations are consistent with reported concentrations in air, amount of rainfall and expected values applying simple radioecological models. The [134Cs]/[137Cs] ratio reported for air (about 1) allows for discrimination between “recent” and “old” 137Cs. Expected 136Cs values fell below the detection limits of the instrumentation, despite large sample masses and long counting times. 相似文献
1000.
Merlin Aydın Hale Tozlu Sebnem Kemaloglu Ayse Aytac Guralp Ozkoc 《Journal of Polymers and the Environment》2011,19(1):11-17
In this study, the influence of alkali (NaOH) treatment on the mechanical, thermal and morphological properties of eco-composites
of short flax fiber/poly(lactic acid) (PLA) was investigated. SEM analysis conducted on alkali treated flax fibers showed
that the packed structure of the fibrils was deformed by the removal non-cellulosic materials. The fibrils were separated
from each other and the surface roughness of the alkali treated flax fibers was improved. The mechanical tests indicated that
the modulus of the untreated fiber/PLA composites was higher than that of PLA; on the other hand the modulus of alkali treated
flax fiber/PLA was lower than PLA. Thermal properties of the PLA in the treated flax fiber composites were also affected.
Tg values of treated flax fiber composites were lowered by nearly 10 °C for 10% NaOH treatment and 15 °C for 30% NaOH treatment.
A bimodal melting behavior was observed for treated fiber composites different than both of neat PLA and untreated fiber composites.
Furthermore, wide angle X-ray diffraction analysis showed that the crystalline structure of cellulose of flax fibers changed
from cellulose-I structure to cellulose-II. 相似文献